A cyanohydridoborato-vanadium(II) complex, trans-[V (NCBH3)(2)(thf)(4)]

Authors
Hedelt, R Schulzke, C Rehder, D
Citation
R. Hedelt et al., A cyanohydridoborato-vanadium(II) complex, trans-[V (NCBH3)(2)(thf)(4)], INORG CH C, 3(6), 2000, pp. 300-302
Citations number
26
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
6
Year of publication
2000
Pages
300 - 302
Database
ISI
SICI code
1387-7003(200006)3:6<300:ACCT(>2.0.ZU;2-L
Abstract
[V(NCBH3)(2)(thf)(4)], the first cyanohydroborato complex of an early trans ition metal, has been generated in the system [V(CO)(6)](-) /I-2/ tolane/Na [NCBH3] in THF. The crystal structure reveals an ideal trans configuration (point group D-2h) with about linear CNBH3- units, and without intermolecul ar (hydrogen bonding) interactions. (C) 2000 Elsevier Science S.A. All righ ts reserved.