Photoluminescence (PL) experiments under high magnetic fields in the Farada
y configuration on nitrogen-doped ZnSe epilayer structures grown by molecul
ar beam epitaxy are applied to study the impurity centers in the compensati
on limit. Following the nitrogen concentration level [N], different regimes
of field dependence of the donor-acceptor pair transitions are reported. T
he wave function shrinkage model gives the mean distance (R) between impuri
ty centers as the critical parameter for this feature. The transitions rela
ted to excitons bound to shallow (I-1) and deep accepters (I-1(P)) are also
discussed. Their field-dependences are observed to be directly connected t
o the nitrogen doping density, and imply different capture rates depending
on the nature of the neutral impurity. (C) 2000 Elsevier Science B.V. All r
ights reserved.