Spin-flip Raman (SFR) scattering is now an established technique for the in
vestigation of semiconductor heterostructures. Because the scattering is re
sonantly enhanced when the laser is adjusted to coincide with the appropria
te excitonic transition, the technique has high sensitivity. It is also hig
hly selective, since the resonance enhancement occurs at different waveleng
ths for scattering by carriers confined under different circumstances. For
electrons, the SFR spectra enable the g-factor to be determined, thus provi
ding tests of band structure theories. The g-factor is sensitive also to qu
antum confinement, when it may become anisotropic. In the case of holes, th
e higher angular momentum (J = 3/2) makes the SFR spectra highly dependent
on the state of strain of the material. Spin-flip signals from localised ex
citons can also be detected. Such signals enable the electron-hole exchange
interactions to be determined and are thus a sensitive probe of the locali
sation properties of the exciton, for example in quantum dots of differing
sizes. Recent developments will be reviewed to illustrate how the technique
can be used to investigate the physics and materials issues associated wit
h II-VI structures. (C) 2000 Elsevier Science B.V. All rights reserved.