Reaction of cyclopropane carboxylic acid derivatives with sulphur tetrafluoride - an example of a diastereoselective ring opening

Authors
Hell, Z Finta, Z Dmowski, W Faigl, F Pustovit, YM Toke, L Harmat, V
Citation
Z. Hell et al., Reaction of cyclopropane carboxylic acid derivatives with sulphur tetrafluoride - an example of a diastereoselective ring opening, J FLUORINE, 104(2), 2000, pp. 297-301
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
104
Issue
2
Year of publication
2000
Pages
297 - 301
Database
ISI
SICI code
0022-1139(200007)104:2<297:ROCCAD>2.0.ZU;2-W
Abstract
Cyclopropane carboxylic acid derivatives can be converted into trifluoromet hyl group-containing compounds using SF4. Ln the case of a bicyclic cyclopr opane carboxylic acid lactone, similar treatment with sulphur tetrafluoride resulted in the cyclopropane ring opening in a diastereoselective manner. (C) 2000 Elsevier Science S.A. All rights reserved.