A blending process involving the mixing of powders of NdFeB and pure cobalt
has been developed. This process has been shown to be an effective and sim
ple way of adding cobalt to the composition. This allows the composition an
d hence properties of the finished magnets to be adjusted subsequent to the
casting and milling of the basic alloy. After standard sintering treatment
s, the cobalt substitutes into the matrix phase, causing a linear increase
in the Curie temperature of 11 degrees C per at% Co in the range 0-10 at% C
o. As the amount of cobalt increases, so the remanence is improved, but the
re is a corresponding decrease in the coercivity. With increasing cobalt co
ntent, the proportion of grain boundary phase decreases and cobalt-containi
ng phases are observed. The increase in remanence is attributed to the incr
eased proportion of Nd-2(Fe, Co)(14)B and the decrease in coercivity is att
ributed to the reduced magnetic isolation of the grains and to the introduc
tion of ferromagnetic, cobalt containing grain boundary phases. (C) 2000 El
sevier Science B.V. All rights reserved.