Synthesis and optical investigations of low molecular weight alkoxy-substituted poly(p-phenylenevinylene)s

Low molecular weight poly(2,5-dialkoxy-1,4-phenylenevinylene) polymers with branched, macrocyclic, and cyclic polyethereal alkoxy chains have been pre pared by Stille cross-coupling reaction between suitable 2,5-dialkoxy-1,4-d iiodobenzenes and (E)-1,2-bis(tributylstannyl)ethene. Spectral line narrowi ng in solution and film under high pulsed excitation intensity is reported. The measurement of the photoluminescence efficiency in film is carried out . The PPV with macrocyclic alkoxy substitution shows higher efficiency but lower damage threshold than the PPV derivative with open alkoxy chains. The potential of these materials in electroluminescent devices is discussed.