Biphasic Wacker-oxidation of 1-octene catalyzed by palladium complexes with modified beta-cyclodextrins

Authors
Karakhanov, E Maximov, A Kirillov, A
Citation
E. Karakhanov et al., Biphasic Wacker-oxidation of 1-octene catalyzed by palladium complexes with modified beta-cyclodextrins, J MOL CAT A, 157(1-2), 2000, pp. 25-30
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
157
Issue
1-2
Year of publication
2000
Pages
25 - 30
Database
ISI
SICI code
1381-1169(20000620)157:1-2<25:BWO1CB>2.0.ZU;2-J
Abstract
New water-soluble palladium complexes with molecular recognition abilities based on beta-cyclodextrin (beta-CD) modified by nitrile-containing groups have been designed. Complexes display high catalytic activity and selectivi ty in two-phase Wacker-oxidation of 1-octene under mild conditions. The cor relation between binding constants for inclusion complexes of beta-CD-based compounds with substrate and the reaction rates has been established. (C) 2000 Elsevier Science B.V. All rights reserved.