Halogen xenon hydrides ClXeH and BrXeH, their deuterated analogues, and ten
tatively the HXeH dihydrides were generated in solid neon matrices and char
acterized by infrared absorption spectroscopy. Preparation of these interes
ting species in the weakly interacting neon matrix, as well as extensive de
nsity functional theory calculations, suggests that their observation is no
t solely due to stabilization by the matrix but that they should be capable
of independent existence.