From a generalized Chapman-Kolmogorov equation to the fractional Klein-Kramers equation

Citation
R. Metzler et J. Klafter, From a generalized Chapman-Kolmogorov equation to the fractional Klein-Kramers equation, J PHYS CH B, 104(16), 2000, pp. 3851-3857
Citations number
52
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
104
Issue
16
Year of publication
2000
Pages
3851 - 3857
Database
ISI
SICI code
1520-6106(20000427)104:16<3851:FAGCET>2.0.ZU;2-#
Abstract
A non-Markovian generalization of the Chapman-Kolmogorov transition equatio n for continuous time random processes governed by a waiting time distribut ion is investigated. It is shown under which conditions a long-tailed waiti ng time distribution with a diverging characteristic waiting time leads to a fractional generalization of the Klein-Kramers equation. From the latter equation a fractional Rayleigh equation and a fractional Fokker-Planck equa tion are deduced. These equations are characterized by a slow, nonexponenti al relaxation of the modes toward the Gibbs-Boltzmann and the Maxwell therm al equilibrium distributions. The derivation sheds some light on the physic al origin of the generalized diffusion and friction constants appearing in the fractional Fokker-Planck equation.