Molecular and crystal, structure of cadmium(II) diisobutyldithiocarbamate {Cd[(i-C4H9)(2)NCS2](2)}(2)

Authors
Glinskaya, LA Zemskova, SM Klevtsova, RF
Citation
La. Glinskaya et al., Molecular and crystal, structure of cadmium(II) diisobutyldithiocarbamate {Cd[(i-C4H9)(2)NCS2](2)}(2), J STRUCT CH, 40(6), 1999, pp. 979-983
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
40
Issue
6
Year of publication
1999
Pages
979 - 983
Database
ISI
SICI code
0022-4766(199911/12)40:6<979:MACSOC>2.0.ZU;2-K
Abstract
Zinc(II) and cadmium(II) diethyldithiocarbamates (ML2) are promising volati le metal chelates having practical applications [I]. It is known that solid chelates ML2 are dimers in which the dithiocarbamate ions perform both cyc lic bidentate and bridging cyclic tridentate functions. Here we report on t he synthesis and molecular and crystal structure of the [Cd(i-Bu2NCS2)(2)]( 2) complex This study was undertaken to investigate the effect of the alkyl substituent on the character of crystal packing.