TERRIGENOUS DEBRIS AND MUSSEL POLLUTION - A DIFFERENTIATION BASED ON TRACE-ELEMENT CONCENTRATION BY MEANS OF MULTIVARIATE-ANALYSIS

Citation
L. Favretto et al., TERRIGENOUS DEBRIS AND MUSSEL POLLUTION - A DIFFERENTIATION BASED ON TRACE-ELEMENT CONCENTRATION BY MEANS OF MULTIVARIATE-ANALYSIS, Analytica chimica acta, 344(3), 1997, pp. 251-259
Citations number
12
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032670
Volume
344
Issue
3
Year of publication
1997
Pages
251 - 259
Database
ISI
SICI code
0003-2670(1997)344:3<251:TDAMP->2.0.ZU;2-7
Abstract
The total content of nine trace elements (Mn, Fe, Co, Ni, Cu, Zn, Cd, Hg and Pb) of the soft edible part of mussels (Mytilus galloprovincial is Lamarck) sampled in two different sites was considered. The first s ampling site was located at the extremity of a pier near the sewage of Trieste in a polluted area of the Muggia Bay (Gulf of Trieste in the Northern Adriatic Sea), whereas unpolluted mussels were simultaneously sampled in the second one, i.e. a hatchery just off the southern extr emity of the bay. The sampling was extended over a year and occurred w ith a frequency of nearly ten days. Both mussel groups had an equal sa mple numerosity (n(1)=n(2)=43) and standard atomic absorption methods were used for all the trace elements. Linear discriminant analysis (LD A) was applied to this two-group sampling in order to test a possible differentiation between the polluted and unpolluted mussels. LDA gave in this two-group sampling a nearly complete separation of scores, whe reas the bidimensional and tridimensional score plots, obtained by mea ns of linear principal component analysis (LPCA), gave a certain degre e of entanglement. The detrital origin of pollutants is also discussed .