Shear melting in lyotropic hexagonal phases

Citation
L. Ramos et al., Shear melting in lyotropic hexagonal phases, LANGMUIR, 16(14), 2000, pp. 5846-5848
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
16
Issue
14
Year of publication
2000
Pages
5846 - 5848
Database
ISI
SICI code
0743-7463(20000711)16:14<5846:SMILHP>2.0.ZU;2-X
Abstract
We use small-angle X-ray scattering to investigate the structures under she ar of surfactant hexagonal phases swollen with oil. Rheology studies of the se materials indicate a shear-induced transition between two states of diff erent viscosity. In the low shear regime, the cylinders are preferentially oriented along the flow and the hexagonal phase exhibits a polycrystalline texture. Unexpectedly, a high shear has the effect of melting the long-rang e two-dimensional (2D) order of the cylinders, leading to a 2D liquid of cy linders strongly aligned along the flow.