A modification of the geometry used in the sin(2) psi technique of X-ray di
ffraction is described. A modified equation for residual stress determinati
on, including geometric adapted F-ij, is presented. This method allows near
surface stress gradients determination and is called pseudo-grazing incide
nce method. The limits of the new technique were first tested on different
powder materials with X-ray radiation produced by conventional tubes and by
a synchrotron radiation source. The technique was finally applied for the
determination of a residual stress profile in a polished molybdenum surface
before and after the deposition of a PVD chromium film. (C) 2000 Elsevier
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