Hydrogen bonds in carboxylic acid-carboxylate systems in solution. 1. In anhydrous, aprotic media

Citation
A. Bruck et al., Hydrogen bonds in carboxylic acid-carboxylate systems in solution. 1. In anhydrous, aprotic media, ORG LETT, 2(14), 2000, pp. 2007-2009
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
14
Year of publication
2000
Pages
2007 - 2009
Database
ISI
SICI code
1523-7060(20000713)2:14<2007:HBICAS>2.0.ZU;2-C
Abstract
GRAPHICS Preliminary NMR studies on hydrogen bonding of carboxylic acid-carboxylate systems in an anhydrous, aprotic solvent are presented. In all cases, a tow -field resonance (16-20 ppm) indicative of strong hydrogen bonding was obse rved. From these results, it seems probable that this characteristic downfi eld shift should be exhibited by all carboxylic acid-carboxylate systems in anhydrous, aprotic media.