New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation of carbonyl compounds with N-formylmorpholine derivatives

Authors
Billard, T Bruns, S Langlois, BR
Citation
T. Billard et al., New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation of carbonyl compounds with N-formylmorpholine derivatives, ORG LETT, 2(14), 2000, pp. 2101-2103
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
14
Year of publication
2000
Pages
2101 - 2103
Database
ISI
SICI code
1523-7060(20000713)2:14<2101:NSRFTN>2.0.ZU;2-C
Abstract
[GRAPHICS] A new stable equivalent of the trifluoromethyl anion has been synthesized f rom fluoroform, It reacts with nonenolizable carbonyl compounds such as the Ruppert's reagent.