Isobaric vapor-liquid equilibria in the systems ethyl 1,1-dimethylethyl ether plus hexane and plus heptane

Authors
Reich, R Cartes, M Segura, H Wisniak, J
Citation
R. Reich et al., Isobaric vapor-liquid equilibria in the systems ethyl 1,1-dimethylethyl ether plus hexane and plus heptane, PHYS CHEM L, 38(2), 2000, pp. 217-232
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICS AND CHEMISTRY OF LIQUIDS
ISSN journal
00319104 → ACNP
Volume
38
Issue
2
Year of publication
2000
Pages
217 - 232
Database
ISI
SICI code
0031-9104(2000)38:2<217:IVEITS>2.0.ZU;2-Z
Abstract
Pure-component vapor pressure of ethyl 1,1-dimethylethyl ether and vapor-li quid equilibrium for the binary systems of ETBE with hexane and with heptan e have been measured at 94 kPa. Both systems deviate slightly from ideal be havior, can be described as regular solutions and do no present an azeotrop e. The activity coefficients and boiling points of the solutions were corre lated with its composition by the Redlich-Kister, Wohl, Wilson, UNIQUAC, NR TL, and Wisniak-Tamir equations.