Influence of transitions among degenerated states of atoms and molecules on some physico-chemical quantities of liquids: Vaporization entropies of liquid 3d-metals

Authors
Gorbachev, MY
Citation
My. Gorbachev, Influence of transitions among degenerated states of atoms and molecules on some physico-chemical quantities of liquids: Vaporization entropies of liquid 3d-metals, PHYS CHEM L, 38(1), 2000, pp. 17-23
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICS AND CHEMISTRY OF LIQUIDS
ISSN journal
00319104 → ACNP
Volume
38
Issue
1
Year of publication
2000
Pages
17 - 23
Database
ISI
SICI code
0031-9104(2000)38:1<17:IOTADS>2.0.ZU;2-X
Abstract
The equation, describing the vaporization entropies of liquid 3d-metals and taking into account the electronic distribution of 3d-metals' atoms, is re ceived by the use of the assumption about the general character of the rela tionship, which characterizes the influence of transitions among degenerate d states of atoms and molecules on physico chemical quantities of liquids. It is shown that the vaporization entropies of these metals can be calculat ed adequately by means of this equation.