Adsorption parameters of n-hexanol on single-crystal faces of bismuth: A regression analysis of the differential capacitance data and comparing the capacitance and chronocoulometry measurements

Authors
Damaskin, BB Baturina, OA Safonov, VA Lust, E Janes, A
Citation
Bb. Damaskin et al., Adsorption parameters of n-hexanol on single-crystal faces of bismuth: A regression analysis of the differential capacitance data and comparing the capacitance and chronocoulometry measurements, RUSS J ELEC, 36(6), 2000, pp. 673-678
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
36
Issue
6
Year of publication
2000
Pages
673 - 678
Database
ISI
SICI code
1023-1935(200006)36:6<673:APONOS>2.0.ZU;2-3
Abstract
The adsorption parameters of n-hexanol on the (111), (01(1) over bar), and (001) faces of single-crystal Bi electrodes are calculated using a nonlinea r regression analysis of nonequilibrium differential capacitance curves wit hin the model of two parallel capacitors supplemented with the Frumkin isot herm. Possible reasons for the discrepancy between the adsorption parameter s obtained from the capacitance and chronocoulometric measurements are disc ussed.