Synergistic effect in bimetallic Ni-Al clusters. Application to efficient catalytic reductive dehalogenation of polychlorinated arenes

Authors
Massicot, F Schneider, R Fort, Y Illy-Cherrey, S Tillement, O
Citation
F. Massicot et al., Synergistic effect in bimetallic Ni-Al clusters. Application to efficient catalytic reductive dehalogenation of polychlorinated arenes, TETRAHEDRON, 56(27), 2000, pp. 4765-4768
Citations number
21
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
27
Year of publication
2000
Pages
4765 - 4768
Database
ISI
SICI code
0040-4020(20000630)56:27<4765:SEIBNC>2.0.ZU;2-B
Abstract
Subnanometric Ni-Al clusters, in situ prepared by reduction of equimolar am ounts of Ni(OAc)(2) and Al(Acac)(3) induced by alkoxide activated sodium hy dride, exhibit a high catalytic activity for efficient reductive dehalogena tion of aliphatic and aromatic halides and polychlorinated arenes. (C) 2000 Elsevier Science Ltd. Ail rights reserved.