Aqua(5,6-dimethyl-1,10-phenanthroline-N,N ')(glycolato-O,O ')copper(II) nitrate

Authors
Medina, G Gasque, L Bernes, S
Citation
G. Medina et al., Aqua(5,6-dimethyl-1,10-phenanthroline-N,N ')(glycolato-O,O ')copper(II) nitrate, ACT CRYST C, 56, 2000, pp. 766-768
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
7
Pages
766 - 768
Database
ISI
SICI code
0108-2701(200007)56:<766:A''N>2.0.ZU;2-W
Abstract
The title compound, [Cu(C2H3O3)(C14H12N2)(H2O)]NO3, is the first example of a mixed copper glycolate compound with a diimine ligand. The copper(II) co mpound lies in a slightly distorted square-pyramidal coordination environme nt with one water molecule coordinated in the apical position. The glycolat e ligand binds to the Cu atom as a chelate through a carboxylate and the al pha-OH O atom which, together with the N atoms of the substituted phenanthr oline, constitute the base of the pyramid.