catena-Poly[[dicyanamido(1,10-phen-anthroline)copper(II)]-mu-dicyanamido]

Authors
Wang, ZM Luo, J Sun, BW Yan, CH Gao, S Liao, CS
Citation
Zm. Wang et al., catena-Poly[[dicyanamido(1,10-phen-anthroline)copper(II)]-mu-dicyanamido], ACT CRYST C, 56, 2000, pp. 786-788
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
7
Pages
786 - 788
Database
ISI
SICI code
0108-2701(200007)56:<786:C>2.0.ZU;2-4
Abstract
The title compound, [Cu(C2N3)(2)(C12H8N2)](n), has a sheet-like structure, built by [Cu(phen)(dca)(2)](n) (phen is 1,10-phenanthroline and dca is dicy anamide) chains which are interconnected by secondary long Cu-N bonds betwe en the chains. The Cu2+ ion is in a distorted tetragonal bipyramidal (5 + 1 ) coordination environment. The sheets stack into the three-dimensional cry stal structure through aromatic interactions between the coordinated phen l igands of adjacent sheets.