Layered zincoarsenate templated by N,N,N ',N '-tetramethylethylenediamine molecules

Authors
Hajem, AA Trojette, B Driss, A Jouini, T
Citation
Aa. Hajem et al., Layered zincoarsenate templated by N,N,N ',N '-tetramethylethylenediamine molecules, ACT CRYST C, 56, 2000, pp. 793-794
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
7
Pages
793 - 794
Database
ISI
SICI code
0108-2701(200007)56:<793:LZTBN'>2.0.ZU;2-5
Abstract
The title compound, N,N,N',N'- tetramethylethylenediammonium diaqua(arsenat e)(hydrogen arsenate)dizinc(II), (C6H18N2)(0.5)[Zn-2 (AsO4)(HAsO4)(H2O)(2)] , is a new zincoarsenate obtained by hydrothermal synthesis. The structure consists of infinite two-dimensional anionic layers alternating with planes containing centrosymmetric organic diprotonated template N,N,N',N'-tetrame thylethylenediammonium cations, [H3NC6 H12NH3](2+). The latter are intercon nected to the framework through hydrogen bonds.