Benzyltriethylammonium 2,2,2,4-tetrachloro-2,5-dihydro-1,2 lambda(5)-oxa-tellurole

Authors
Zukerman-Schpector, J Camillo, RL Comasseto, JV Cunha, LOR Caracelli, I
Citation
J. Zukerman-schpector et al., Benzyltriethylammonium 2,2,2,4-tetrachloro-2,5-dihydro-1,2 lambda(5)-oxa-tellurole, ACT CRYST C, 56, 2000, pp. 897-898
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
7
Pages
897 - 898
Database
ISI
SICI code
0108-2701(200007)56:<897:B2L>2.0.ZU;2-9
Abstract
The geometry around the Te atom in the anion in C13H22N+. C3H3Cl4OTe- is di storted pseudo-octahedral with three Cl atoms and the O atom forming the eq uatorial plane, and the C atom lying opposite the tellurium lone pair. Dist ances and angles are: Te-O 2.0120 (18), Te-C 2.072 (2), Te-Cl 2.5239 (7), 2 .5283 (7) and 2.5577 (7) Angstrom; O-Te-C 81.61 (9), O-Te-Cl 90.69 (6), 90. 99 (6) and 168.13 (5), C- Te-Cl 87.13 (8), 86.64 (8) and 86.59 (8), and Cl- Te-Cl 87.02 (2), 90.00 (3) and 173.24 (3)degrees. The anions are arranged i n an infinite zigzag chain parallel to the a axis through a secondary Te .. . Cl bond [3.8391 (8) Angstrom].