Bis[methylenebis(diphenylphosphine)-P,P ']nickel(II) diperchlorate

Authors
Li, YZ Liu, JC Wang, ZP Li, QX Sun, GC Wang, LF Xia, CG
Citation
Yz. Li et al., Bis[methylenebis(diphenylphosphine)-P,P ']nickel(II) diperchlorate, ACT CRYST C, 56, 2000, pp. E286-E287
Citations number
4
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
7
Pages
E286 - E287
Database
ISI
SICI code
0108-2701(200007)56:<E286:B'D>2.0.ZU;2-M
Abstract
The title compound, [Ni(Ph2PCH2PPh2)(2)](ClO4)(2), was synthesized and its structure determined crystallographically. The Ni atom lies on an inversion centre and is at the center of a square formed by four P atoms which are n ecessarily coplanar. The Ni-P distances are 2.2188 (5) and 2.2322 (5) Angst rom, and the P- Ni-P angle is 73.12 (3)degrees. The unique perchlorate anio n is not coordinated to the Ni atom.