Dicyclohexylammonium 2,4-dichlorophenoxyacetate and (2,4-dichlorophenoxyacetato-O,O ')bis(triphenylphosphine-P)silver(I)

Authors
Subramanian, RR Anandan, SS Kwek, KH Low, KS Raj, SSS Fun, HK Razak, IA Hanna, JV Ng, SW
Citation
Rr. Subramanian et al., Dicyclohexylammonium 2,4-dichlorophenoxyacetate and (2,4-dichlorophenoxyacetato-O,O ')bis(triphenylphosphine-P)silver(I), ACT CRYST C, 56, 2000, pp. E292-E294
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
7
Pages
E292 - E294
Database
ISI
SICI code
0108-2701(200007)56:<E292:D2A(>2.0.ZU;2-R
Abstract
The monoclinic cell of dicyclohexylammonium 2,4-dichlorophenoxyacetate cont ains four C12H24N+. C5H8Cl2O3- ion pairs. The ammonium N atom is hydrogen b onded to the oxygen ends of two carboxyl groups to form a 12-membered O-C-O ... HNH ... O-C-O ... HNH ring. In (2,4-dichlorophenoxylacetato)bis(triphe nylphosphine)silver(I), [Ag(C8H5Cl2 O-3)(C18H15P)(2)], the carboxyl CO2 uni t chelates to the Ag atom in an anisobidentate manner [Ag-O = 2.436 (2) and 2.517 (2) Angstrom]; the Ag atom shows distorted tetrahedral geometry.