Photoluminescence studies and read/write process of a strong two-photon absorbing chromophore

The optical properties of a fluorene-based chromophore exhibiting a high tw o-photon absorption cross section have been investigated both in the pure s tate and as a guest-host system in poly(N-vinylcarbazole). Upon irradiation with a helium cadmium (He-Cd) laser at 325 nm, the guest-host sample exhib its a blueshift with a maximum emission at 459 nm. Information written onto the samples in the blue can also be read using an Ar+ laser. The chromopho re undergoes a chemical change upon irradiation in air, and has been found to no longer exhibit upconversion after this transformation. Infrared analy sis of the sample (the chromophore) before and after irradiation was carrie d out, and the spectra suggest the formation of a new conjugated species. O ther applications we have developed using this phenomenon include the succe ssful writing of optical device structures in polymer films where the AF-50 is a guest material. (C) 2000 American Institute of Physics. [S0003-6951(0 0)04729-X].