Two long-term no-till corn production studies, representing different soil
texture, consistently showed higher leaching of atrazine [2-chloro-4-(ethyl
amino)-6-(isopropylamino)-s-triazine] to groundwater in a silt loam soil th
an in a sandy loam soil. A laboratory leaching study was initiated using in
tact soil cores from the two sites to determine whether the soil texture co
uld account for the observed differences. Six intact soil cores (16 cm dia
by 20 cm high) were collected from a four-year old no-till corn plots at ea
ch of the two locations (ca. 25 km apart). All cores were mounted in funnel
s and the saturated hydraulic conductivity (K-sat) was measured. Three core
s (from each soil texture) with the lowest K-sat were mixed and repacked. A
ll cores were surface treated with 1.7 kg ai ha(-1) [ring-C-14] atrazine, s
ubjected to simulated rainfall at a constant 12 mm h(-1) intensity until ne
arly 3 pore volume of leachate was collected and analyzed for a total of C-
14. On an average, nearly 40% more of atrazine was leached through the inta
ct silt loam than the sandy loam soil cores. For both the intact and repack
ed cores, the initial atrazine leaching rates were higher in the silt loam
than the sandy loam soils, indicating that macropore flow was a more promin
ent mechanism for atrazine leaching in the silt loam soil. A predominance o
f macropore flow in the silt loam soil, possibly due to greater aggregate s
tability, may account for the observed leaching patterns for both field and
laboratory studies. (C) 2000 Elsevier Science Ltd. All rights reserved.