Predispersed solvent extraction (PDSE) is a new method for separating solut
es from aqueous solution by solvent extraction and one which has shown prom
ise for extraction from extremely dilute solution very efficient and very q
uick. The use of colloidal liquid aphrons in predispersed solvent extractio
n may ameliorate the problems such as emulsion formation, reduction of inte
rfacial mass transfer and low interfacial mass transfer areas in solvent ex
traction process. In present paper, colloidal liquid aphrons are successful
ly generated using kerosene as a solvent, tributyl phosphate(TBP) as an ext
ractant, sodium dodecyl benzene sulphate(SDBS) as surfactant in aqueous pha
se and Tween-80 in oil phase. Extraction of phenol from dilute solution was
studied by using colloidal liquid aphrons and colloidal gas aphrons in a s
emi-batch extraction column. It has been found that the PDSE process is mor
e suitable for extraction of dilute solutions. It has also been discovered
that the PDSE process has a great advantage over traditional single-stage e
xtraction process.