A comparison of different experimental techniques for metallic particle siz
e evaluation including light diffraction, scanning electron microscope anal
ysis and nitrogen adsorption is presented. Nitrogen adsorption as an approp
riate experimental method for particle size evaluation is proposed. Certain
aspects of chemical reactivity of micron and submicron aluminum powders in
the air, using thermogravimetry and differential thermal analysis (TG/DTA)
, are discussed.
Three metallic Al powders were analyzed: S-400 (Reynolds Co.), ALEX (Argoni
de Corp.) and WARP-1 (Ceramic and Materials Processing, Inc.). TG/DTA analy
sis revealed that S-400 (specific surface area = 0.3 m(2)/g) does not react
below melting point of Al (2% conversion); ALEX powder (specific surface a
rea = 12.0 m(2)/g) starts reacting around T = 440 degrees C and 16% reacts
before melting point temperature is reached. WARP-1 samples (specific surfa
ce area between 16.0 and 26.5 m(2)/g) react already at T = 200 degrees C an
d 25 wt% of aluminum is oxidized below melting point temperature. Different
ial thermal analysis did not discover any "stored" energy in S - 400 or ALE
X materials; however, WARP-1 samples released thermal energy already at 130
and 230 degrees C, which is assigned to "stored energy".