FTIR spectroscopic characterization of chlorinated camphenes and bornenes in technical toxaphene

The unsaturated C-10-components and their amounts in technical toxaphene ha ve been characterized with the help of column chromatography/FTIR spectrosc opy using the typical absorption bands of the >C=C< valence bonds in the re gion between 1590 and 1655 cm(-1). The sum of unsaturated compounds is appr oximately 5%. The results of the analysis of 2500 fractions collected show that ca. 70% of the unsaturated compounds are chlorocamphenes, while the re st are chlorobornenes. Most of the chlorocamphenes contain a monochlorinate d exo-double bond (2.37% w/w of the whole mixture) and only a minor part co ntain either an unsubstituted (0.67%) or a dichlorinated axial double bond (0.11%). in the case of chlorobornenes, congeners with dichlorinated double bonds dominate (1.24%), while the amounts of chlorobornenes with mono- and unsubstituted double bonds are negligible (0.01% and 0.12%).