COMPARATIVE-ANALYSIS OF THE SURFACE MOBILITY OF PROTONS AND OTHER SINGLE-CHARGED CATIONS ON THE SURFACE OF RUTILE-TYPE OXIDES

Authors
ZYUBINA T DOBROVOLSKY Y
Citation
T. Zyubina et Y. Dobrovolsky, COMPARATIVE-ANALYSIS OF THE SURFACE MOBILITY OF PROTONS AND OTHER SINGLE-CHARGED CATIONS ON THE SURFACE OF RUTILE-TYPE OXIDES, Solid state ionics, 97(1-4), 1997, pp. 59-62
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
97
Issue
1-4
Year of publication
1997
Pages
59 - 62
Database
ISI
SICI code
0167-2738(1997)97:1-4<59:COTSMO>2.0.ZU;2-Q
Abstract
Quantum mechanical modelling of the transport of sodium, lithium and h ydrogen over the surface of oxides of group TV elements having rutile- type structure, showed that the structure and geometry of the conducti ng channels are primarily dependent on the nature of mobile cations, w hereas energy barriers for transfer via these channels depends on both the size of the elementary cell of the oxide and the radius of the ca tion.