AC BEHAVIOR OF PROTON-CONDUCTING SOLID ELECTROLYTES BASED ON SULFOSALICYLIC ACID IN HYDROGEN ATMOSPHERE

Authors
BUKUN N RODIONOV V MIKHAILOVA A DOBROVOLSKY Y
Citation
N. Bukun et al., AC BEHAVIOR OF PROTON-CONDUCTING SOLID ELECTROLYTES BASED ON SULFOSALICYLIC ACID IN HYDROGEN ATMOSPHERE, Solid state ionics, 97(1-4), 1997, pp. 257-260
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
97
Issue
1-4
Year of publication
1997
Pages
257 - 260
Database
ISI
SICI code
0167-2738(1997)97:1-4<257:ABOPSE>2.0.ZU;2-8
Abstract
The conductivity (sigma) of sulphosalicylic acid and its composites wi th iron(III) sulphosalicylate (1:4 molar) is measured using impedance spectroscopy and the Hebb-Wagner polarization method. The conductance is found to be purely protonic with typical values of sigma(25 degrees C) = 4.1 x 10(-4) and 3.0 x 10(-4) S cm(-1), respectively. The exchan ge currents at TiHx \ H+-solid electrolyte interphase boundaries incre ase with increasing partial pressure of H-2 in mixtures with argon.