N. Sata et al., FABRICATION OF PROTON CONDUCTING THIN-FILMS OF SRZRO3 AND SRCEO3 AND THEIR FUNDAMENTAL CHARACTERIZATION, Solid state ionics, 97(1-4), 1997, pp. 437-441
Proton conducting thin films of SrZrO3 and SrCeO3 were fabricated by t
he pulsed laser ablation method using ArF excimer laser. The thin film
s of SrCeO3 and SrZrO3 were grown in the [100] direction on the SrTiO3
(100) substrate and in the [211] direction on the MgO(100) substrate a
nd on the Al2O3 substrate. The Raman scattering spectra show that the
thin films grown in the low P-o2 contain lots of oxygen ion vacancies
compared to bulk crystals.