Displacive vs. order-disorder in structural phase transitions

Citation
Jm. Perez-mato et al., Displacive vs. order-disorder in structural phase transitions, FERROELECTR, 236(1-4), 2000, pp. 93-103
Citations number
11
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
FERROELECTRICS
ISSN journal
00150193 → ACNP
Volume
236
Issue
1-4
Year of publication
2000
Pages
93 - 103
Database
ISI
SICI code
0015-0193(2000)236:1-4<93:DVOISP>2.0.ZU;2-O
Abstract
The quantitative assessment of the displacive degree of a structural phase transition is discussed both from a microscopical and an empirical viewpoin t. Using Monte Carlo results for the Phi(4) model as a qualitative guide, t he relation between both perspectives is shown. Based on the general trends observed, an empirical parameter for describing the displacive degree of a ny structural phase transition is proposed. The Rhodes-Wolfarth factor exte nded to ferroelectrics by Tokunaga [J. Phys. Sec. Jpn (1988) 4275] is a rea lization of this general parameter for the particular case of proper ferroe lectrics. The power and limitations of such approach are discussed.