Vapor-liquid equilibrium data and critical points for the system H2S+COS. Extension of the PSRK group contribution equation of state

Authors
Guilbot, P Theveneau, P Baba-Ahmed, A Horstmann, S Fischer, K Richon, D
Citation
P. Guilbot et al., Vapor-liquid equilibrium data and critical points for the system H2S+COS. Extension of the PSRK group contribution equation of state, FLU PH EQUI, 170(2), 2000, pp. 193-202
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
FLUID PHASE EQUILIBRIA
ISSN journal
03783812 → ACNP
Volume
170
Issue
2
Year of publication
2000
Pages
193 - 202
Database
ISI
SICI code
0378-3812(20000428)170:2<193:VEDACP>2.0.ZU;2-F
Abstract
Isothermal vapor-liquid equilibrium data for the binary system hydrogen sul fide + carbonyl sulfide were measured in the temperature range from 232 to 293 K using the static synthetic technique. From the isothermal P - x data, the azeotropic conditions were derived. The critical line of this system w as visually detected in a flow apparatus. Interaction parameters for this b inary system were fitted simultaneously to all the experimental VLE and cri tical data for the Predictive Soave-Redlich-Kwong group contribution equati on of state. (C) 2000 Elsevier Science B.V, All rights reserved.