Citation
S. Bernhard et al., Time-resolved IR studies of [Re(LL)(CO)(4)](+), INORG CHEM, 39(14), 2000, pp. 3107
Citations number
35
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669
→ ACNP
Volume
39
Issue
14
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000710)39:14<3107:TISO[>2.0.ZU;2-8
Abstract
Ground-state and time-resolved infrared data are resented in the v(CO) regi
on for [Re(LL)(CO)(4)](+) (LL is 2,2'-bipyridine (bpy), 4,4'-dimethyl-2,2'-
bipyridine (dmb), or 1,10-phenanthroline (phen)) in 1,2-dichloroethane at 2
98 K following 354.7 nm excitation. The data demonstrate formation of a uni
que excited state for the [Re(LL)(CO)(4)](+) species followed by loss of a
single carbonyl ligand to form a fac-Re(CO)(3) solvento complex.