Heterobimetallic cluster of [WOS3](2-) with copper(I) chloride: synthesis and structural characterization of a new dinuclear complex [Me4N](2)[WOS3(CuCl)]

Authors
Rahman, ABMS Boller, H Klepp, KO
Citation
Abms. Rahman et al., Heterobimetallic cluster of [WOS3](2-) with copper(I) chloride: synthesis and structural characterization of a new dinuclear complex [Me4N](2)[WOS3(CuCl)], INORG CHIM, 305(1), 2000, pp. 91-94
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
305
Issue
1
Year of publication
2000
Pages
91 - 94
Database
ISI
SICI code
0020-1693(20000714)305:1<91:HCO[WC>2.0.ZU;2-6
Abstract
Orange-yellow crystals of the new dinuclear complex [Me4N](2)[WOS3(CuCl)] w ere formed by the reaction of [Me4N](2),[WOS3] with CuCl in a mixture of 1: 1 MeCN/CH2Cl2 at room temperature. The new compound has been characterized by infrared and mass spectrometry. The crystal structure of the complex has been determined from single crystal diffractometer data (Mo K alpha-radiat ion) and it is characterized as binuclear complex anions [WOS3(CuCl)](2-). (C) 2000 Elsevier Science S.A. All rights reserved.