M. Deschamps et al., Nuclear magnetic resonance study of xenon-131 interacting with surfaces: Effective Liouvillian and spectral analysis, J CHEM PHYS, 113(4), 2000, pp. 1630-1640
Coherent and dissipative phenomena induced by transient adsorption of xenon
-131 on a glass surface are studied by nuclear magnetic resonance spectrosc
opy. We report the results of multiple-quantum filtered experiments over a
range of temperatures, covering different relaxation regimes. An analysis i
n terms of an effective Liouvillian is proposed, the complex eigenvalues of
which may be directly extracted from the experimental spectra. For this pu
rpose, we apply recently developed techniques for spectral analysis, in par
ticular decimated signal diagonalization. The results are compared with a c
onventional fit of the multiple-quantum build-up behavior. (C) 2000 America
n Institute of Physics. [S0021-9606(00)00628-0].