Synthesis and optical ligand-to-ligand charge transfer of Zn(2, 6-bis(benzimidazolyl)pyridine)-(3,4-toluenedithiolate)

Authors
Leirer, M Knor, G Vogler, A
Citation
M. Leirer et al., Synthesis and optical ligand-to-ligand charge transfer of Zn(2, 6-bis(benzimidazolyl)pyridine)-(3,4-toluenedithiolate), J COORD CH, 50(2), 2000, pp. 141-144
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
50
Issue
2
Year of publication
2000
Pages
141 - 144
Database
ISI
SICI code
0095-8972(2000)50:2<141:SAOLCT>2.0.ZU;2-4
Abstract
The complex Zn[(BzImH)(2)Py](TDT) with (BzImH)(2)Py=2,6-bis(benzimidazolyl] )pyridine and TDT2-=3,4- toluenedithiolate was prepared and characterized s pectroscopically. The yellow colour of this compound is caused by an absorp tion band (lambda(max)=369 nm in ethanol), which is assigned to a ligand-to -ligand charge transfer transition from TDT2- to the(BzImH)(2)Py ligand.