Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

Authors
Mincheva, N Todorov, T Angelova, O Bailey, PJ Mitewa, M
Citation
N. Mincheva et al., Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine, J COORD CH, 50(2), 2000, pp. 169-176
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
50
Issue
2
Year of publication
2000
Pages
169 - 176
Database
ISI
SICI code
0095-8972(2000)50:2<169:SASOPC>2.0.ZU;2-F
Abstract
The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphe nylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been ob served and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2 ] has been determined by X-ray diffraction methods. The ligands are coordin ated as neutral monodentate molecules to the metal centre through their imi ne nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidin e)(4)](2+) and was isolated by precipitation with ClO4-.