Geothermal convection in carbonate platforms could drive massive dolomitiza
tion by supplying mass transport of magnesium over long periods and at temp
eratures high enough to overcome kinetic limitations. Reactive-transport si
mulations based on Enewetak Atoll show dolomitization in a thin band at a p
ermeability contrast near the base of the platform, which is consistent wit
h field observations of dolomitized Eocene deposits. Dolomitization is pred
icted at approximately 6% per My at temperatures of 45-60 degrees C, and co
mplete dolomitization could be accomplished in similar to 16 My. Calcium en
richment of pare fluids and upward transport of these fluids is established
early, prior to 30 ky. (C) 2000 Elsevier Science B.V. All rights reserved.