Environmental degradation of materials during wet storage of spent nuclearfuels

Wet storage is the predominant mode of storage of spent nuclear fuels. Due to legislation and other constraints, many countries do not reprocess spent fuels and have to store these for extended periods in spent fuel storage p ools (SFSPs). Although the water chemistry of the: pool is benign, certain factors such as stagnancy of water, crevices, and galvanic contacts between various materials of the fuel clad and the lining of the pools can result in unexpected localized corrosion. In this study, the susceptibility to loc alized corrosion of aluminum-1S (Al-1S), Zircaloy-2, and type 304 stainless steel (SS) has been assessed using accelerated tests with crevice bent bea m (CBB) assemblies, The pool water constituents have been analyzed and elec trochemical potentials (ECPs) measured in water samples drawn from differen t locations of the pool. The ECP has also been measured in situ, in the poo ls. It has been demonstrated that under conditions of crevice and galvanic contact, aluminum clad fuels from research reactors are prone to localized corrosion even in the benign environments of a SFSP, The ECP experiments in dicate the importance of surface condition of the material and irradiation on degradation of various materials due to corrosion.