A tight binding technique is employed to study the influence of the size of
the unit cell on molecular dynamics simulations of liquid selenium at 870
K. Systems with 69, 138, 276 and 552 atoms have been studied within the Fer
mi operator expansion method. The Green-Kubo formula has been used to calcu
late the shear viscosity for all systems from the off-diagonal component of
the stress tensor. No dependence on the cell size could be found within th
e error bars defined by statistical accuracy. For the two smallest systems
calculations up to 60 ps have been performed where the viscosities become i
dentical. These findings indicate that the recently reported disagreement o
f DFT calculations and experiments on the viscosity of liquid selenium at 8
70 K must be attributed to a deficiency in the chosen exchange correlation
functional rather than size effects.