In the context of a detailed investigation of the luminescent properties of
the Na2-xAgxZnP2O7 compounds, the structure of the pure sodium phosphates
was "revisited." The crystal structure of Na2ZnP2O7 has been determined by
X-ray diffraction using single crystals. A new model explaining the actual
large unit cell (a = b = 2177.1(3) pm, c = 1028.5(2) pm, P4(2)/n, Z = 32) w
as determined by assuming the existence of twins. The structure is made up
of [ZnP2O7] layers consisting of corners sharing [P2O7] groups and [ZnO4] t
etrahedra, and the sodium atoms are located between the layers in 7- or 8-f
old coordinated sites. This model is discussed with respect to the crystal
chemistry of the monovalent cation zinc phosphate. (C) 2000 Academic Press.