Synthesis and structure of Li[(C5H4)CH2CH2(TACN-Pr-i(2))] . A lithium complex supported by a Cp/TACN-Pr-i(2) ligand

Authors
Qian, BX Henling, LM Peters, JC
Citation
Bx. Qian et al., Synthesis and structure of Li[(C5H4)CH2CH2(TACN-Pr-i(2))] . A lithium complex supported by a Cp/TACN-Pr-i(2) ligand, ORGANOMETAL, 19(14), 2000, pp. 2805-2808
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
14
Year of publication
2000
Pages
2805 - 2808
Database
ISI
SICI code
0276-7333(20000710)19:14<2805:SASOL.>2.0.ZU;2-B
Abstract
The new ligand (C5H5)CH2CH2(TACN-Pr-i(2)) (TACN-Pr-i(2) = 4,7-diisopropyl-1 ,4,7-triaza-1-cyclononyl) has been prepared and structurally characterized as its lithium complex, Li[(C5H4)CH2CH2(TACN-Pr-i(2))]. The method of prepa ration employed nucleophilic addition of the lithium amide complex [Li(TACN -Pr-i(2))](2) to spiro-[2.4]hepta-4,6-diene. The crystal structure of [Li(T ACN-Pr-i(2))](2) is also presented.