Stereoselective synthesis of stable 1,4-diionic phosphorus compounds mediated by a vinyltriphenylphosphonium salt

Authors
Yavari, I Samadizadeh, M Jabbari, A
Citation
I. Yavari et al., Stereoselective synthesis of stable 1,4-diionic phosphorus compounds mediated by a vinyltriphenylphosphonium salt, PHOSPHOR SU, 160, 2000, pp. 43-49
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
160
Year of publication
2000
Pages
43 - 49
Database
ISI
SICI code
1042-6507(2000)160:<43:SSOS1P>2.0.ZU;2-3
Abstract
The addition reaction of triphenylphosphine to ethyl phenylpropiolate in th e presence of strong CH-acids, such as Meldrum's acid, N,N'-dimethylbarbitu ric acid or indane-1,3-dione leading to highly functionalized 1,4-diionic o rganophosphorus compounds is reported. The stable crystalline phosphorus be taines were characterized by H-1, C-13 and P-31 nuclear magnetic resonance (NMR) spectroscopy, mass spectrometry and elemental analysis.