Citation
D. Sikora et T. Gajda, A facile synthesis of diethyl 1-(isothiocyano)alkylphosphonates, PHOSPHOR SU, 157, 2000, pp. 201-210
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507
→ ACNP
Volume
157
Year of publication
2000
Pages
201 - 210
Database
ISI
SICI code
1042-6507(2000)157:<201:AFSOD1>2.0.ZU;2-2
Abstract
Novel, diethyl 1-(isothiocyano)alkylphosphonates 3 have been efficiently sy
nthesized via a one-pot reaction of diethyl 1-azidoalkylphosphonates 1 with
triphenylphosphine, followed by in situ transformation of thus formed phos
phazenes 2 with carbon disulfide. Application of the title compounds in the
synthesis of diethyl (N-phenylthioureido)- and (benzothiazol-2-ylamino)met
hylphosphonates was also described.