Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, thianols and thiolactones

Authors
Bonini, BF Franchini, MC Fochi, M Mangini, S Mazzanti, G Ricci, A
Citation
Bf. Bonini et al., Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, thianols and thiolactones, PHOSPHOR SU, 153, 1999, pp. 315-316
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
153
Year of publication
1999
Pages
315 - 316
Database
ISI
SICI code
1042-6507(1999)153:<315:ETAIFT>2.0.ZU;2-X
Abstract
Thietanols, thiolanols and thianols can be obtained by a fluoride-mediated cyclization of Z-alpha-silyl vinyl sulphides containing a -carbonylic funct ion in the chain bonded to the sulfur. The condensative cyclization of -car boxy-Z-alpha-silyl enethiols leads to unsaturated silylated thiolactones.