Crotonaldehyde hydrogenation over alumina- and silica-supported Pt-Sn catalysts of different composition. In situ DRIFT study

Alumina- and silica-supported bimetallic Pt-Sn catalysts with different Pt/ Sn atomic ratios have been prepared by using the bimetallic complex cis-[Pt Cl(SnCl3)(PPh3)(2)], the monometallic complex cis-[PtCl2(PPh3)(2)] and SnCl 2 as metal precursors. Catalysts have been characterised by X-ray diffracti on and transmission electron microscopy techniques, including energy-disper sive X-ray microanalysis, electron diffraction experiments and lattice-frin ge microanalysis. The phase composition of the different catalysts has been related to the catalytic behaviour in the vapour phase hydrogenation of cr otonaldehyde (but-2-enal). Results show that catalysts containing platinum- tin alloy phases with large particles are more selective towards the hydrog enation of the carbonyl bond to yield crotyl alcohol. The presence of oxidi sed tin species on the surface of the large alloy particles promotes the hy drogenation of the carbonyl bond. In situ diffuse reflectance infrared spec troscopy studies of crotonaldehyde adsorption under He or H-2 reveal differ ences between bimetallic catalysts and monometallic, and these differences have been related to the different catalytic behaviour of the catalysts.