In this paper the effect of the inclusion of two different thermotropic liq
uid crystalline polymers, namely Rodrun 3000 and Vectra A950, in a PP matri
x is analyzed with particular attention to the gas transport and mechanical
properties of the extruded blend films. The experiments, conducted on PP/R
odrun 3000 and PP/Vectra A950 films, have shown that the presence of TLCPs,
also at low percentages, modify the properties of the thermoplastic matrix
in a manner depending on the degree of compatibility and interfacial adhes
ion between the two components of the blends. Moreover. the effect of a mal
eic anhydride grafted PP (MAP), used as compatibilizing agent, on the prope
rties and morphology of the PP/Rodrun 3000 system was examined. It was foun
d that the addition of the MAP determines an increase in the barrier proper
ties and in toughness of the films compared to those without MAP.